Crystal structure of lithium diisopropylamide (LDA): an infinite helical arrangement composed of near-linear nitrogen-lithium-nitrogen units with four units per turn of helix

Barnett, N.D.R and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1991) Crystal structure of lithium diisopropylamide (LDA): an infinite helical arrangement composed of near-linear nitrogen-lithium-nitrogen units with four units per turn of helix. Journal of the American Chemical Society, 113 (21). pp. 8187-8188. ISSN 1520-5126 (https://doi.org/10.1021/ja00021a066)

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Abstract

Although the number of crystal structure reports of organic lithium derivatives has mushroomed over the past decade or so, a report of the most important lithium reagent, indeed, one of the most utilized reagents throughout organic synthesis, lithium diisopropylamide (LDA), has been conspicuously absent.

ORCID iDs

Barnett, N.D.R, Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, Clegg, William and O'Neil, Paul A.;