The first magnesium amide trimer, magnesio-1,8-diaminonaphthalene center dot hexamethylphosphoramide: introducing an unprecedented cage assembly incorporating an Mg-3 unit within a N-6 trigonal prism

Clegg, W and Horsburgh, L and Mulvey, Robert and Rowlings, R (1996) The first magnesium amide trimer, magnesio-1,8-diaminonaphthalene center dot hexamethylphosphoramide: introducing an unprecedented cage assembly incorporating an Mg-3 unit within a N-6 trigonal prism. Chemical Communications (15). pp. 1739-1740. ISSN 1364-548X (https://doi.org/10.1039/CC9960001739)

Abstract

Doubly deprotonating 1,8-diaminonaphthalene with dibutylmagnesium in the presence of hmpa leads to the formation of the title compound, which establishes a new aggregation state and cage architecture within magnesium amide chemistry; the departure from classical, non-cage, organomagnesium structures can be attributed to the bifunctional and steric design of the involved 'dianion'.

ORCID iDs

Mulvey, Robert ORCID: https://orcid.org/0000-0002-1015-2564

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• Item metadata

  Item type:	Article
  ID code:	38193
  Dates:	Date Event 7 August 1996 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	06 Mar 2012 12:45
  Last modified:	14 Feb 2025 05:42
  URI:	https://strathprints.strath.ac.uk/id/eprint/38193