Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

Spicer, Mark and Hanton, L.R. and Cordes, D.B. (2007) Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine. Crystal Growth and Design, 7. pp. 328-336. ISSN 1528-7483 (https://doi.org/10.1021/cg0604632)

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Abstract

The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.

ORCID iDs

Spicer, Mark ORCID logoORCID: https://orcid.org/0000-0002-6000-5677, Hanton, L.R. and Cordes, D.B.;
CORE (COnnecting REpositories)