Renner-Teller interaction, high angular momentum states and spin-orbit interaction in the electronic spectrum of ND2

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Duxbury, G. and Reid, J.P. (2007) Renner-Teller interaction, high angular momentum states and spin-orbit interaction in the electronic spectrum of ND2. Molecular Physics, 105 (11-12). pp. 1603-1618. ISSN 0026-8976 (https://doi.org/10.1080/00268970701384480)

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Abstract

A rotational and vibrational analysis has been made of the ND2 (A) over tilde (2) A(1) -(X) over tilde B-2(1) emission spectrum produced from the ultraviolet laser induced dissociation of both jet cooled and room temperature deuterated ammonia. By a combination of these experimental data with model calculation based upon the stretch-bender Renner-Teller Hamiltonian, and a previous analysis of the NH2 spectrum, most of the strong features in the emission spectra have been assigned. The spectrum consists of transitions from a narrow distribution of high angular momentum states peaking at K-a values of 7 in the jet condition, and 8 at room temperature. Information has also been gained on the high angular momentum states of previously inaccessible higher bending levels from v(2)=2 to v(2)=6 in the (X) over tilde B-2(1) state.

  • Item type:Article
    ID code:31290
    Dates:
    Date
    Event
    2007
    Published
    Subjects:Science > Physics
    Department:Faculty of Science > Physics
    Depositing user: Pure Administrator
    Date deposited:13 Jul 2011 08:56
    Last modified:11 Nov 2024 09:45
    URI:https://strathprints.strath.ac.uk/id/eprint/31290
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