10,11-dihydrodiindeno[1,2-b : 2 ',1 '-d]thiophene

Tools

Afonina, I. and Coles, S.J. and Hursthouse, M.B. and Kanibolotsky, A.L. and Skabara, P.J. (2008) 10,11-dihydrodiindeno[1,2-b : 2 ',1 '-d]thiophene. Acta Crystallographica Section E: Structure Reports, 64 (Part 1). o167. ISSN 1600-5368 (https://doi.org/10.1107/S1600536807063684)

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Abstract

The title compound, C18H12S, comprises five fused rings forming an essentially planar molecule, with a total puckering amplitude (Q) of 0.032 Å and a maximum deviation from the mean plane of 0.014 (4) Å for the C atoms of the methylene groups. A crystallographic mirror plane orthogonal to the molecular plane passes through the S atom and the midpoint of the opposite C-C bond within the central five-membered ring. The molecules lie in layers, forming edge-to-face C-H interactions, with a separation of 2.66 Å between one H atom of the methylene group and the centroid of an adjacent indene ring.

ORCID iDs

Afonina, I., Coles, S.J., Hursthouse, M.B., Kanibolotsky, A.L. ORCID logoORCID: https://orcid.org/0000-0003-3991-6297 and Skabara, P.J.;
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