Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

Blair, V.L. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. (2008) Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure. Chemical Communications (London) (42). pp. 5426-5428. ISSN 0009-241X (http://dx.doi.org/10.1039/b812147h)

Abstract

Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

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• Item metadata

  Item type:	Article
  ID code:	19449
  Dates:	Date Event 2008 Published
  Subjects:	UNSPECIFIED
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	26 May 2010 09:03
  Last modified:	08 Apr 2024 17:32
  URI:	https://strathprints.strath.ac.uk/id/eprint/19449