Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

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Cross, R.J. and Kennedy, A.R. and Manojlovic-Muir, L.J. (1993) Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2. Acta Crystallographica Section C: Crystal Structure Communications, 49 (6). pp. 1146-1148. ISSN 0108-2701 (http://dx.doi.org/10.1107/S0108270192012666)

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Abstract

In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.

ORCID iDs

Cross, R.J., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Manojlovic-Muir, L.J.;
  • Item type:Article
    ID code:1324
    Dates:
    Date
    Event
    June 1993
    Published
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user:Users 45 not found.
    Date deposited:28 Jun 2006
    Last modified:11 Nov 2024 08:11
    URI:https://strathprints.strath.ac.uk/id/eprint/1324
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