cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)
Kennedy, A.R. and Sloss, S.W. and Spicer, M.D. (1997) cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II). Acta Crystallographica Section C: Crystal Structure Communications, 53 (3). pp. 292-294. ISSN 0108-2701 (http://dx.doi.org/10.1107/S0108270196014229)
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The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.
ORCID iDs
Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015, Sloss, S.W. and Spicer, M.D. ORCID: https://orcid.org/0000-0002-6000-5677;-
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Item type: Article ID code: 1305 Dates: DateEventMarch 1997PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Users 45 not found. Date deposited: 26 Jun 2006 Last modified: 11 Nov 2024 08:12 URI: https://strathprints.strath.ac.uk/id/eprint/1305
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