Rational design of molecular sheets composed of interconnecting eight and twenty-four membered rings: use of lithiated aggregates to control network assembly

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Henderson, K.W. and Kennedy, A.R. and MacDonald, L. and McDougall, D.J. (2003) Rational design of molecular sheets composed of interconnecting eight and twenty-four membered rings: use of lithiated aggregates to control network assembly. Inorganic Chemistry, 42 (9). pp. 2839-2841. ISSN 1520-510X (http://dx.doi.org/10.1021/ic034115q)

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Abstract

The lithiated (organo)sulfonylacetonitrile complex [MeSO2CHCNLi·THF] (3) has been prepared and structurally characterized in order to demonstrate that well-known molecular aggregates of s-block metals may be used as building blocks in the controlled assembly of complex supramolecular architectures. The solid state structure of 3 can be described as a novel basket-weaved, 2-D network, composed of (SO2Li)2 'dimeric' rings joined via 'interdimer' donation of nitrile units.

ORCID iDs

Henderson, K.W., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, MacDonald, L. and McDougall, D.J.;
CORE (COnnecting REpositories)