Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

Kennedy, A.R. and Khalaf, A.I. and Suckling, C.J. and Waigh, R.D. (2004) Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate. Acta Crystallographica Section E: Structure Reports, 60 (8). pp. 1188-1190. ISSN 1600-5368 (http://www.blackwell-synergy.com/doi/full/10.1107/...)

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Abstract

In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.

ORCID iDs

Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Khalaf, A.I. ORCID logoORCID: https://orcid.org/0000-0001-9162-7527, Suckling, C.J. and Waigh, R.D.;
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