A novel asymptotically-consistent approximation for integral evaporation from a spherical cap droplet

Wray, Alexander W. and Moore, Madeleine R. (2024) A novel asymptotically-consistent approximation for integral evaporation from a spherical cap droplet. Journal of Engineering Mathematics, 146 (1). 4. ISSN 0022-0833 (https://doi.org/10.1007/s10665-024-10355-1)

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Abstract

The total evaporation rate due to a volatile capillarity-dominated droplet diffusively evaporating into the surrounding gas is a critically important quantity in industrial and engineering applications such as Q/OLED screen manufacturing. However, the analytical expression in terms of integrals in toroidal coordinates can be unwieldy in applications, as well as expensive to compute. Therefore, sim-ple yet highly-accurate approximate solutions are frequently used in practical settings. Herein we present a new approximate form that is both accurate and fast to compute, but also retains the correct asymptotic behaviour in the key physical regimes, namely hydrophilic and superhydrophobic substrates, and a hemispherical droplet. We illustrate this by comparison to several previous approximations and, in particular, illustrate its use in calculating droplet lifetimes, as well as approximating the local evaporative flux.