Arylboronic acid catalyzed C-alkylation and allylation reactions using benzylic alcohols

Estopiñá-Durán, Susana and Mclean, Euan B. and Donnelly, Liam J. and Hockin, Bryony M. and Taylor, James E. (2020) Arylboronic acid catalyzed C-alkylation and allylation reactions using benzylic alcohols. Organic Letters, 22 (19). pp. 7547-7551. ISSN 1523-7060 (https://doi.org/10.1021/acs.orglett.0c02736)

Preview

Text. Filename: Estopi_Dur_n_etal_OL_2020_Arylboronic_acid_catalyzed_C_alkylation_and_allylation_reactions_using_benzylic_alcohols.pdf Final Published Version License: Download (1MB)| Preview

Abstract

: The arylboronic acid catalyzed dehydrative Calkylation of 1,3-diketones and 1,3-ketoesters using secondary benzylic alcohols as the electrophile is reported, forming new C−C bonds (19 examples, up to 98% yield) with the release of water as the only byproduct. The process is also applicable to the allylation of benzylic alcohols using allyltrimethylsilane as the nucleophile (12 examples, up to 96% yield).

• Share and Export
  

  RDF+XMLBibTeXRIOXX2 XMLRDF+N-TriplesJSONDublin CoreAtomSimple MetadataReferMETSHTML CitationASCII CitationOpenURL ContextObjectEndNoteOpenURL ContextObject in SpanMODSMPEG-21 DIDLEP3 XMLData Cite XMLRIS (EndNote Online, Zotero, Ref manager, etc)RDF+N3Multiline CSV
• Item metadata

  Item type:	Article
  ID code:	83247
  Dates:	Date Event 22 September 2020 Published 16 August 2020 Accepted
  Subjects:	Science > Chemistry > Organic chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	17 Nov 2022 10:12
  Last modified:	17 Apr 2024 00:51
  URI:	https://strathprints.strath.ac.uk/id/eprint/83247