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Crystal engineering towards highly ordered polymeric structures of 1,3-dithiole-2-thione-dihalogen adducts

Skabara, P.J. and Bricklebank, N. and Berridge, R. and Long, S. and Light, M.E. and Coles, S.J. and Hursthouse, M.B. (2000) Crystal engineering towards highly ordered polymeric structures of 1,3-dithiole-2-thione-dihalogen adducts. Journal of the Chemical Society, Dalton Transactions, 2000 (19). pp. 3235-3236. ISSN 0300-9246

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Abstract

The crystal structure of an iodine monobromide adduct of dimethyl 1,3-dithiole-2-thione-4,5-dicarboxylate reveals a layered polymeric network of donor and acceptor molecules linked primarily through S ... I-Br charge-transfer and hydrogen bonded interactions.