A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

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Hay, Moya A. and Sarkar, Arup and Craig, Gavin A. and Marriott, Katie E. R. and Wilson, Claire and Rajaraman, Gopalan and Murrie, Mark (2020) A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii). Chemical Communications, 56 (50). pp. 6826-6829. ISSN 1359-7345 (https://doi.org/10.1039/D0CC02382E)

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Abstract

The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.

  • Item type:Article
    ID code:72488
    Dates:
    Date
    Event
    25 June 2020
    Published
    6 May 2020
    Published Online
    6 May 2020
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:27 May 2020 15:03
    Last modified:12 Dec 2024 09:48
    URI:https://strathprints.strath.ac.uk/id/eprint/72488
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