Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Tools

Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9226 (https://doi.org/10.1039/C8DT01997E)

[thumbnail of Collet-etal-DT2018-Slow-magnetic-relaxation-[CoIICoIII2]-complex-containing-high-magnetic-anisotropy-trigonal-bipyramidal-CoII]
Preview
 Text. Filename: Collet_etal_DT2018_Slow_magnetic_relaxation_CoIICoIII2_complex_containing_high_magnetic_anisotropy_trigonal_bipyramidal_CoII.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo
Download (802kB)| Preview

Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

ORCID iDs

Collet, Alexandra, Craig, Gavin A., Heras Ojea, María José ORCID logoORCID: https://orcid.org/0000-0002-9290-5178, Bhaskaran, Lakshmi, Wilson, Claire, Hill, Stephen and Murrie, Mark;
CORE (COnnecting REpositories)