A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

Tools

Heras Ojea, María José and Lorusso, Giulia and Craig, Gavin A. and Wilson, Claire and Evangelisti, Marco and Murrie, Mark (2017) A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring. Chemical Communications, 53 (35). pp. 4799-4802. ISSN 1359-7345 (https://doi.org/10.1039/C7CC02243C)

[thumbnail of Ojea-etal-CC-2017-A-topologically-unique-alternating]
Preview
 Text. Filename: Ojea_etal_CC_2017_A_topologically_unique_alternating.pdf
Final Published Version
License: Creative Commons Attribution 3.0 logo
Download (2MB)| Preview

Abstract

The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

ORCID iDs

Heras Ojea, María José ORCID logoORCID: https://orcid.org/0000-0002-9290-5178, Lorusso, Giulia, Craig, Gavin A. ORCID logoORCID: https://orcid.org/0000-0003-3542-4850, Wilson, Claire, Evangelisti, Marco and Murrie, Mark;
CORE (COnnecting REpositories)