A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

Ojea, María José Heras and Lorusso, Giulia and Craig, Gavin A. and Wilson, Claire and Evangelisti, Marco and Murrie, Mark (2017) A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring. Chemical Communications, 53 (35). pp. 4799-4802. ISSN 1359-7345

[img]
Preview
Text (Ojea-etal-CC-2017-A-topologically-unique-alternating)
Ojea_etal_CC_2017_A_topologically_unique_alternating.pdf
Final Published Version
License: Creative Commons Attribution 3.0 logo

Download (2MB)| Preview

    Abstract

    The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.