Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation

Andrikopoulos, Prokopis C. and Armstrong, David R. and Graham, David V. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Talmard, Christine (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 1521-3773 (https://doi.org/10.1002/anie.200500379)

Abstract

Conventional meta-deprotonation of toluene leads to resonance of Benzylanionen. But with a new type of bimetallic metalation, the sodium-mediated Magnesierung, can shift the thermodynamic meta-deprotonation in the ring.

ORCID iDs

Hevia, Eva ORCID: https://orcid.org/0000-0002-3998-7506

Kennedy, Alan R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, Robert E. ORCID: https://orcid.org/0000-0002-1015-2564

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• Item metadata

  Item type:	Article
  ID code:	651
  Dates:	Date Event 30 May 2005 Published 21 April 2005 Published Online
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	28 Mar 2006
  Last modified:	11 Nov 2024 08:28
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/651