Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS)

Ojeda-Amador, Ana I. and Martínez-Martínez, Antonio J. and Robertson, Gemma M. and Robertson, Stuart D. and Kennedy, Alan R. and O'Hara, Charles T. (2017) Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS). Dalton Transactions, 46 (19). pp. 6392-6403. ISSN 1477-9234

[img]
Preview
 Text (Ojeda-Amador-etal-DT2017-Exploring-the-solid-state-and-solution-structural-chemistry)
Ojeda_Amador_etal_DT2017_Exploring_the_solid_state_and_solution_structural_chemistry.pdf
Final Published Version
License: Creative Commons Attribution 3.0 logo
Download (2MB)| Preview

    Abstract

    The structural chemistry of eleven donor complexes of the important Brønsted base potassium 1,1,1,3,3,3-hexamethyldisilazide (KHMDS) has been studied. Depending on the donor, each complex adopted one of four general structural motifs. Specifically, in this study the donors employed were toluene (to give polymeric 1 and dimeric 2), THF (dimeric 3), N,N,N',N'-tetramethylethylenediamine (TMEDA) (dimeric 4), (R,R)-N,N,N',N'-tetramethyl-1,2-diaminocyclohexane [(R,R)-TMCDA] (dimeric 5), 12-crown-4 (dimeric 6), N,N,N',N'-tetramethyldiaminoethyl ether (TMDAE) (tetranuclear dimeric 8 and monomeric 10), N,N,N',N',N''-pentamethyldiethylentriamine (PMDETA) (tetranuclear dimeric 7), tris[2-dimethyl(amino)ethyl]amine (Me6TREN) (tetranuclear dimeric 9) and tris{2-(2-methoxyethoxy)ethyl}amine (TMEEA) (monomeric 11). The complexes were also studied in solution by 1H and 13C NMR spectroscopy as well as DOSY NMR spectroscopy.

    Author(s):Ojeda-Amador, Ana I. ORCID logoORCID: https://orcid.org/0000-0003-3991-2851, Martínez-Martínez, Antonio J., Robertson, Gemma M., Robertson, Stuart D. ORCID logoORCID: https://orcid.org/0000-0002-9330-8770, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and O'Hara, Charles T. ORCID logoORCID: https://orcid.org/0000-0002-1691-1568
    Item type:Article
    ID code:60447
    Keywords:structural chemistry, Brønsted base potassium, structural motifs, spectroscopic analysis, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:18 Apr 2017 09:20
    Last modified:16 Aug 2019 03:00
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/60447
    Export data:
    CORE (COnnecting REpositories)