Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS)

Ojeda-Amador, Ana I. and Martínez-Martínez, Antonio J. and Robertson, Gemma M. and Robertson, Stuart D. and Kennedy, Alan R. and O'Hara, Charles T. (2017) Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS). Dalton Transactions, 46 (19). pp. 6392-6403. ISSN 1477-9234

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    Abstract

    The structural chemistry of eleven donor complexes of the important Brønsted base potassium 1,1,1,3,3,3-hexamethyldisilazide (KHMDS) has been studied. Depending on the donor, each complex adopted one of four general structural motifs. Specifically, in this study the donors employed were toluene (to give polymeric 1 and dimeric 2), THF (dimeric 3), N,N,N',N'-tetramethylethylenediamine (TMEDA) (dimeric 4), (R,R)-N,N,N',N'-tetramethyl-1,2-diaminocyclohexane [(R,R)-TMCDA] (dimeric 5), 12-crown-4 (dimeric 6), N,N,N',N'-tetramethyldiaminoethyl ether (TMDAE) (tetranuclear dimeric 8 and monomeric 10), N,N,N',N',N''-pentamethyldiethylentriamine (PMDETA) (tetranuclear dimeric 7), tris[2-dimethyl(amino)ethyl]amine (Me6TREN) (tetranuclear dimeric 9) and tris{2-(2-methoxyethoxy)ethyl}amine (TMEEA) (monomeric 11). The complexes were also studied in solution by 1H and 13C NMR spectroscopy as well as DOSY NMR spectroscopy.

    ORCID iDs

    Ojeda-Amador, Ana I. ORCID logoORCID: https://orcid.org/0000-0003-3991-2851, Martínez-Martínez, Antonio J., Robertson, Gemma M., Robertson, Stuart D. ORCID logoORCID: https://orcid.org/0000-0002-9330-8770, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and O'Hara, Charles T.;
    • Item type:Article
      ID code:60447
      Dates:
      Date
      Event
      15 May 2017
      Published
      3 May 2017
      Published Online
      13 April 2017
      Accepted
      Keywords:structural chemistry, Brønsted base potassium, structural motifs, spectroscopic analysis, Chemistry, Chemistry(all)
      Subjects:Science > Chemistry
      Department:Faculty of Science > Pure and Applied Chemistry
      Depositing user: Pure Administrator
      Date deposited:18 Apr 2017 09:20
      Last modified:01 Dec 2021 01:58
      Related URLs:
      URI:https://strathprints.strath.ac.uk/id/eprint/60447
    CORE (COnnecting REpositories)