Layer-by-layer self-assembly of bisdendrons : an unprecedented route to multilayer thin films

Lee, Ok-Joo and Maraval, Valérie and Caminade, Anne-Marie and Chung, Kyungwha and Lau, King Hang Aaron and Shin, Kwanwoo and Majoral, Jean-Pierre and Knoll, Wolfgang and Kim, Dong Ha (2016) Layer-by-layer self-assembly of bisdendrons : an unprecedented route to multilayer thin films. Macromolecular Research, 24 (10). pp. 851-855. ISSN 1598-5032 (https://doi.org/10.1007/s13233-016-4128-z)

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Abstract

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino end groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.

ORCID iDs

Lee, Ok-Joo, Maraval, Valérie, Caminade, Anne-Marie, Chung, Kyungwha, Lau, King Hang Aaron ORCID logoORCID: https://orcid.org/0000-0003-3676-9228, Shin, Kwanwoo, Majoral, Jean-Pierre, Knoll, Wolfgang and Kim, Dong Ha;
  • Item type:Article
    ID code:57321
    Dates:
    Date
    Event
    31 October 2016
    Published
    1 September 2016
    Published Online
    25 July 2016
    Accepted
    18 May 2016
    Submitted
    Notes:The final publication is available at Springer via http://link.springer.com/journal/13233
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:09 Aug 2016 08:42
    Last modified:11 Nov 2024 11:28
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/57321
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