Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes : reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order

Schweicher, Guillaume and Lemaur, Vincent and Niebel, Claude and Ruzié, Christian and Diao, Ying and Goto, Osamu and Lee, Wen-Ya and Kim, Yeongin and Arlin, Jean-Baptiste and Karpinska, Jolanta and Kennedy, Alan R. and Parkin, Sean R. and Olivier, Yoann and Mannsfeld, Stefan C. B. and Cornil, Jérôme and Geerts, Yves H. and Bao, Zhenan (2015) Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes : reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. Advanced Materials, 27 (19). pp. 3066-3072. ISSN 1521-4095 (https://doi.org/10.1002/adma.201500322)

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Abstract

A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm(2) V(-1) s(-1) .

ORCID iDs

Schweicher, Guillaume, Lemaur, Vincent, Niebel, Claude, Ruzié, Christian, Diao, Ying, Goto, Osamu, Lee, Wen-Ya, Kim, Yeongin, Arlin, Jean-Baptiste, Karpinska, Jolanta, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Parkin, Sean R., Olivier, Yoann, Mannsfeld, Stefan C. B., Cornil, Jérôme, Geerts, Yves H. and Bao, Zhenan;
  • Item type:Article
    ID code:52870
    Dates:
    Date
    Event
    20 May 2015
    Published
    9 April 2015
    Published Online
    1 March 2015
    Accepted
    Notes:This is the accepted version of the following article: Schweicher, G., Lemaur, V., Niebel, C., Ruzié, C., Diao, Y., Goto, O., ... Bao, Z. (2015). Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. Advanced Materials. 10.1002/adma.201500322, which has been published in final form at http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201500322/abstract.
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:06 May 2015 08:34
    Last modified:11 Nov 2024 11:04
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/52870
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