Inside cover: The synthesis of highly active iridium(I) complexes and their application in catalytic hydrogen isotope exchange (Adv. Synth. Catal. 17/2014)

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Brown, Jack A. and Cochrane, Alison Ruth and Irvine, Stephanie and Kerr, William J. and Mondal, Bhaskar and Parkinson, John A. and Paterson, Laura C. and Reid, Marc and Tuttle, Tell and Andersson, Shalini and Nilsson, Göran N. (2014) Inside cover: The synthesis of highly active iridium(I) complexes and their application in catalytic hydrogen isotope exchange (Adv. Synth. Catal. 17/2014). Advanced Synthesis and Catalysis, 356 (17). p. 3474. ISSN 1615-4150 (https://doi.org/10.1002/adsc.201401054)

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Abstract

The inside cover picture, by Kerr and co-workers depicts a series of robust, yet highly active Ir(I) complexes bearing specifically encumbered N-heterocyclic carbene and phosphine ligands. These complexes are extremely effective in hydrogen isotope exchange processes (with D or T), with low catalyst loadings, good levels of selectivity, and broad directing group applicability. The labelling of several complex drug molecules further highlights the catalysts’ utility. Mechanistic insight into the operation of these catalysts has also been provided by a combination of NMR and theoretical DFT studies.

ORCID iDs

Brown, Jack A., Cochrane, Alison Ruth, Irvine, Stephanie, Kerr, William J. ORCID logoORCID: https://orcid.org/0000-0002-1332-785X, Mondal, Bhaskar, Parkinson, John A. ORCID logoORCID: https://orcid.org/0000-0003-4270-6135, Paterson, Laura C., Reid, Marc ORCID logoORCID: https://orcid.org/0000-0003-4394-3132, Tuttle, Tell, Andersson, Shalini and Nilsson, Göran N.;
  • Item type:Article
    ID code:50517
    Dates:
    Date
    Event
    24 November 2014
    Published
    18 November 2014
    Published Online
    Notes:This is the accepted version of the following article: The synthesis of highly active iridium(I) complexes and their application in catalytic hydrogen isotope exchange, Brown, J. A., Cochrane, A. R., Irvine, S., Kerr, W., Mondal, B., Parkinson, J. A., Paterson, L., Reid, M., Tuttle, T., Andersson, S. & Nilsson, G. N. 2014 In : Advanced Synthesis and Catalysis., which has been published in final form at: http://onlinelibrary.wiley.com/doi/10.1002/adsc.201401054/
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Technology and Innovation Centre > Bionanotechnology
    Depositing user: Pure Administrator
    Date deposited:25 Nov 2014 12:00
    Last modified:26 Nov 2024 01:08
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/50517
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