Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation
Smart, P. and Mason, C A and Loader, J R and Meijer, Anthony J.H.M. and Florence, Alastair and Shankland, Kenneth and Fletcher, Ashleigh and Thompson, S P and Brunelli, Michela and Hill, A H and Brammer, Lee (2013) Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation. Chemistry - A European Journal, 19 (11). pp. 3552-3557. ISSN 0947-6539
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MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal-organic framework [Zn2(camph) 2(py)2]×2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn2(camph)2] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands.
Creators(s): |
Smart, P., Mason, C A, Loader, J R, Meijer, Anthony J.H.M., Florence, Alastair ![]() ![]() | Item type: | Article |
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ID code: | 47373 |
Keywords: | solid-state reactions, X-ray diffraction, density functional calculations, metal–organic frameworks, post-synthetic modification, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Engineering > Chemical and Process Engineering Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences Technology and Innovation Centre > Continuous Manufacturing and Crystallisation (CMAC) |
Depositing user: | Pure Administrator |
Date deposited: | 08 Apr 2014 09:23 |
Last modified: | 20 Jan 2021 21:09 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/47373 |
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