Non-dispersive hole transport in a soluble poly(p-phenylene vinylene)

Inigo, A R and Tan, C H and Fann, W and Huang, Y S and Perng, G Y and Chen, S A (2001) Non-dispersive hole transport in a soluble poly(p-phenylene vinylene). Advanced Materials, 13 (7). 504–508. ISSN 0935-9648 (https://doi.org/10.1002/1521-4095(200104)13:7<504:...)

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Abstract

Understanding the relationship between charge transport and morphology is critical for improving the efficiency of conjugatcd polymer-based devices. Time of flight measurements are used here to examine hole transport in films of poly(2-methoxy-5-(2'-ethylhexoxy)-1,4,-phenylene) (MEH-PPV). Films cast from three different solvents, toluene, p-xylene. and chlorobenzene, are investigated. It is shown that the MEH-PPV films can exhibit either nondispersive or dispersive transport. depending on the solvent used.