Mechanistic exploration of the palladium-catalysed process for the synthesis of benzoxazoles and benzothiazoles

Bochatay, Valentin and Boissarie, Patrick and Murphy, John A and Suckling, Colin and Lang, Stuart (2013) Mechanistic exploration of the palladium-catalysed process for the synthesis of benzoxazoles and benzothiazoles. Journal of Organic Chemistry, 78 (4). pp. 1471-1477. ISSN 0022-3263

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Abstract

A convenient one-pot palladium-catalyzed cascade process for the prepn. of both benzoxazoles and benzothiazoles has been developed. While these reactions proceed to give similar compds. the mechanisms governing the processes are different as are the exptl. conditions employed.