Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols
Picon, Sylvain and Rawling, Michael and Campbell, Matthew and Tomkinson, Nick (2012) Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols. Organic Letters, 14 (24). pp. 6250-6253. ISSN 1523-7060
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Abstract
The effect of fluorinated alcohols on the dihydroxylation of alkenes using cyclopropyl malonoyl peroxide is described. Addition of perfluorotert-butyl alcohol to a toluene solution of alkene and peroxide increases the rate of product formation and the stereoselectivity observed, providing a simple and effective method for acceleration of this important
Creators(s): |
Picon, Sylvain, Rawling, Michael, Campbell, Matthew ![]() ![]() | Item type: | Article |
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ID code: | 42477 |
Keywords: | alkene dihydroxylation , malonoyl peroxides , catalysis, fluorinated alcohols, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 07 Jan 2013 16:11 |
Last modified: | 20 Jan 2021 20:29 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/42477 |
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