Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols

Picon, Sylvain and Rawling, Michael and Campbell, Matthew and Tomkinson, Nick (2012) Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols. Organic Letters, 14 (24). pp. 6250-6253. ISSN 1523-7060 (https://doi.org/10.1021/ol3030154)

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Abstract

The effect of fluorinated alcohols on the dihydroxylation of alkenes using cyclopropyl malonoyl peroxide is described. Addition of perfluorotert-butyl alcohol to a toluene solution of alkene and peroxide increases the rate of product formation and the stereoselectivity observed, providing a simple and effective method for acceleration of this important

ORCID iDs

Picon, Sylvain, Rawling, Michael, Campbell, Matthew ORCID logoORCID: https://orcid.org/0000-0002-6003-7257 and Tomkinson, Nick ORCID logoORCID: https://orcid.org/0000-0002-5509-0133;
  • Item type:Article
    ID code:42477
    Dates:
    Date
    Event
    21 December 2012
    Published
    Keywords:alkene dihydroxylation , malonoyl peroxides , catalysis, fluorinated alcohols, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:07 Jan 2013 16:11
    Last modified:30 Sep 2022 00:57
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/42477
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