Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols

Picon, Sylvain and Rawling, Michael and Campbell, Matthew and Tomkinson, Nick (2012) Alkene dihydroxylation with malonoyl peroxides : catalysis using fluorinated alcohols. Organic Letters, 14 (24). pp. 6250-6253. ISSN 1523-7060 (https://doi.org/10.1021/ol3030154)

Abstract

The effect of fluorinated alcohols on the dihydroxylation of alkenes using cyclopropyl malonoyl peroxide is described. Addition of perfluorotert-butyl alcohol to a toluene solution of alkene and peroxide increases the rate of product formation and the stereoselectivity observed, providing a simple and effective method for acceleration of this important

ORCID iDs

Campbell, Matthew ORCID: https://orcid.org/0000-0002-6003-7257

Tomkinson, Nick ORCID: https://orcid.org/0000-0002-5509-0133

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• Item metadata

  Item type:	Article
  ID code:	42477
  Dates:	Date Event 21 December 2012 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	07 Jan 2013 16:11
  Last modified:	28 Feb 2025 17:35
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/42477