Picture map of Europe with pins indicating European capital cities

Open Access research with a European policy impact...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the European Policies Research Centre (EPRC).

EPRC is a leading institute in Europe for comparative research on public policy, with a particular focus on regional development policies. Spanning 30 European countries, EPRC research programmes have a strong emphasis on applied research and knowledge exchange, including the provision of policy advice to EU institutions and national and sub-national government authorities throughout Europe.

Explore research outputs by the European Policies Research Centre...

Chemiluminescence detection of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and related nitramine explosives

Donaldson, David N. and Barnett, Neil W. and Agg, Kent M. and Graham, Duncan and Lenehan, Claire E. and Prior, Chad and Lim, Kieran F. and Francis, Paul S. (2012) Chemiluminescence detection of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and related nitramine explosives. Talanta, 88. pp. 743-748. ISSN 0039-9140

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

A simple controlled chemical reduction of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and related nitramine compounds with zinc amalgam generates species that elicit intense chemiluminescence with tris(2,2'-bipyridine)ruthenium(III), which extends this widely utilised chemiluminescence reagent to a new class of analyte and presents a sound chemical basis for a screening test for nitramine high explosives. Examination of the chemiluminescence profiles under stopped-flow conditions revealed contributions from multiple transient species formed in the initial reduction step.