Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation

Fawcett, John and Griffiths, Gerry A and Percy, Jonathan and Pintat, Stephane and Smith, Clive A and Spencer, Neil S and Uneyama, Emi (2004) Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation. Chemical Communications, 2004 (3). pp. 302-303. ISSN 1359-7345

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    Abstract

    Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.

    Creators(s): Fawcett, John, Griffiths, Gerry A, Percy, Jonathan ORCID logoORCID: https://orcid.org/0000-0001-8636-2704, Pintat, Stephane, Smith, Clive A, Spencer, Neil S and Uneyama, Emi;
    Item type:Article
    ID code:38971
    Keywords:difluorosugar analogues, difluorinated cyclooctenones, hydroxyl groups, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:04 Apr 2012 15:45
    Last modified:20 Jan 2021 20:04
    URI:https://strathprints.strath.ac.uk/id/eprint/38971
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