Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation

Fawcett, John and Griffiths, Gerry A and Percy, Jonathan and Pintat, Stephane and Smith, Clive A and Spencer, Neil S and Uneyama, Emi (2004) Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation. Chemical Communications, 2004 (3). pp. 302-303. ISSN 1359-7345

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Abstract

Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.

Item type:	Article
ID code:	38971
Keywords:	difluorosugar analogues, difluorinated cyclooctenones, hydroxyl groups, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Pure Administrator
Date deposited:	04 Apr 2012 15:45
Last modified:	23 Sep 2017 02:23
URI:	https://strathprints.strath.ac.uk/id/eprint/38971
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