Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation

Fawcett, John and Griffiths, Gerry A and Percy, Jonathan and Pintat, Stephane and Smith, Clive A and Spencer, Neil S and Uneyama, Emi (2004) Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation. Chemical Communications, 2004 (3). pp. 302-303. ISSN 1359-7345 (https://doi.org/10.1039/b313813e)

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Abstract

Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.

ORCID iDs

Percy, Jonathan ORCID: https://orcid.org/0000-0001-8636-2704

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  Item type:	Article
  ID code:	38971
  Dates:	Date Event 2004 Published
  Keywords:	difluorosugar analogues, difluorinated cyclooctenones, hydroxyl groups, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	04 Apr 2012 15:45
  Last modified:	25 May 2023 09:12
  URI:	https://strathprints.strath.ac.uk/id/eprint/38971