Fluorinated succinic acid derivatives from new refrigerants via ozonolysis of haloalkenes

Brown, Samantha J and Corr, Stuart and Percy, Jonathan (2000) Fluorinated succinic acid derivatives from new refrigerants via ozonolysis of haloalkenes. Tetrahedron Letters, 41 (27). pp. 5269-5273. ISSN 0040-4039 (https://doi.org/10.1016/S0040-4039(00)00804-2)

Abstract

Fluoro- and di-fluoro allylic alcohols obtained from HFC-134a and HCFC-133a were transformed through [3,3]-sigmatropic rearrangements into 3-fluoro-4-halo-4-alkenoates with variable substitution at the 2- and 3-positions. Ozonolysis of the haloalkenes afforded the corresponding acyl halides which could be trapped with nucleophiles to afford fluorinated succinic acid derivatives in which the two carboxylic acid groups were differentiated.

ORCID iDs

Percy, Jonathan ORCID: https://orcid.org/0000-0001-8636-2704

• Share and Export
  

  MPEG-21 DIDLASCII CitationHTML CitationRefWorksMETSSimple MetadataRDF+XMLMultiline CSVEndNoteEP3 XMLBibTeXRDF+N3AtomData Cite XMLMODSJSONOpenURL ContextObject in SpanRDF+N-TriplesDublin CoreReferOpenURL ContextObjectRIOXX2 XMLRIS (EndNote Online, Zotero, Ref manager, etc)
• Item metadata

  Item type:	Article
  ID code:	38919
  Dates:	Date Event 1 July 2000 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	03 Apr 2012 15:40
  Last modified:	11 Nov 2024 10:06
  URI:	https://strathprints.strath.ac.uk/id/eprint/38919