Formal total synthesis of (+/-)-alpha- and beta-cedrene by preparation of cedrone. construction of the tricyclic carbon skeleton by the use of a highly efficient intramolecular khand annulation

Kerr, W.J. and McLaughlin, M. and Morrison, A.J. and Pauson, P.L. (2001) Formal total synthesis of (+/-)-alpha- and beta-cedrene by preparation of cedrone. construction of the tricyclic carbon skeleton by the use of a highly efficient intramolecular khand annulation. Organic Letters, 3 (19). pp. 2945-2948. ISSN 1523-7060 (https://doi.org/10.1021/ol016054a)

Abstract

The cedrene carbon skeleton was rapidly assembled from a simple monocyclic precursor by the strategic use of a high yielding intramolecular Khand cyclization reaction. Further synthetic manipulations provided a concise formal total synthesis of α- and β-cedrene.

ORCID iDs

Kerr, W.J. ORCID: https://orcid.org/0000-0002-1332-785X

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• Item metadata

  Item type:	Article
  ID code:	37976
  Dates:	Date Event 20 September 2001 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	28 Feb 2012 14:36
  Last modified:	30 Jan 2025 01:35
  URI:	https://strathprints.strath.ac.uk/id/eprint/37976