ORGN 140-8-Aryl menthamine-derived scaffolds for iminium ion catalysis

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Ruda, Antonio M. and Cavill, Julie L. and Tomkinson, Nicholas C. O. (2006) ORGN 140-8-Aryl menthamine-derived scaffolds for iminium ion catalysis. Abstracts of papers - American Chemical Society, 232. 140-ORGN. ISSN 0065-7727

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Abstract

This poster will describe a novel series of mol. scaffolds for the acceleration of iminium ion catalyzed processes. Drawing inspiration from Corey's 8-Ph menthol chiral auxiliary we have developed a concise synthesis of a new family of secondary amines and investigated their catalytic activity in the Diels-Alder reaction. Importantly, starting from (+)-pulegone as the source of chirality the nature of the asym. induction in the catalytic reaction can be altered by use of either the cis- or the trans-catalyst. Our investigations into variation of the nature of the arom. to modulate a proposed face-face π-π interaction in the transition state will also be reported. [on SciFinder(R)]

ORCID iDs

Ruda, Antonio M., Cavill, Julie L. and Tomkinson, Nicholas C. O. ORCID logoORCID: https://orcid.org/0000-0002-5509-0133;
  • Item type:Article
    ID code:36064
    Dates:
    Date
    Event
    10 September 2006
    Published
    Notes:CAPLUS AN 2006:862282(Conference; Meeting Abstract; Computer Optical Disk)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:21 Nov 2011 16:58
    Last modified:11 Nov 2024 10:01
    URI:https://strathprints.strath.ac.uk/id/eprint/36064
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