Kinetics of iminium ion catalysis

Evans, Gareth and Gibbs, Timothy J. K. and Jenkins, Robert L. and Coles, Simon J. and Hursthouse, Michael B. and Platts, James A. and Tomkinson, Nicholas C. O. (2008) Kinetics of iminium ion catalysis. Agewandte Chemie-International Edition, 47 (15). pp. 2820-2823. ISSN 1433-7851

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Abstract

Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.