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Open Access research with a European policy impact...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the European Policies Research Centre (EPRC).

EPRC is a leading institute in Europe for comparative research on public policy, with a particular focus on regional development policies. Spanning 30 European countries, EPRC research programmes have a strong emphasis on applied research and knowledge exchange, including the provision of policy advice to EU institutions and national and sub-national government authorities throughout Europe.

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Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

Cross, R.J. and Kennedy, A.R. and Manojlovic-Muir, L.J. (1993) Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2. Acta Crystallographica Section C: Crystal Structure Communications, 49 (6). pp. 1146-1148. ISSN 0108-2701

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Abstract

In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.