The structure of lithium garnets : cation disorder and clustering in a new family of fast li+ conductors

Cussen, E. (2006) The structure of lithium garnets : cation disorder and clustering in a new family of fast li+ conductors. Chemical Communications (London), 2006. pp. 412-413. ISSN 0009-241X (https://doi.org/10.1039/b514640b)

[thumbnail of 312157.pdf]
Preview
PDF. Filename: 312157.pdf
Final Published Version

Download (293kB)| Preview

Abstract

The structure of the fast lithium-ion conducting garnets Li5La3M2O12 (M = Ta, Nb) reveals Li+ on both tetrahedral and octahedral sites and suggests that the latter are responsible for the observed Li+ mobility via a clustering mechanism