Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

Hevia, E. and Armstrong, David R. and Kennedy, A. and Mulvey, R.E. (2006) Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation. Organometallics, 25. pp. 2415-2418. ISSN 0276-7333 (http://dx.doi.org/10.1021/om060216v)

Full text not available in this repository.Request a copy

Abstract

Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts present in the crystalline trimetallic product.

ORCID iDs

Hevia, E. ORCID logoORCID: https://orcid.org/0000-0002-3998-7506, Armstrong, David R., Kennedy, A. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564;
CORE (COnnecting REpositories)