Homoleptic crown n-heterocyclic carbene complexes

McKie, Ross and Murphy, J.A. and Park, S.R. and Spicer, M.D. and Zhou, S. (2007) Homoleptic crown n-heterocyclic carbene complexes. Agewandte Chemie-International Edition, 46 (34). pp. 6525-6528. ISSN 1433-7851 (https://doi.org/10.1002/anie.200702138)

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Abstract

The first metal N-heterocyclic carbene complexes derived from a cyclic tetraimidazolium salt show a remarkable versatility of ligand conformation and coordination geometry. With PdII, a mononuclear square-planar complex is obtained, but with CuI and AgI, an unprecedented dinuclear motif with a short metal–metal interaction is observed (see structure; N blue, C white ellipsoids, H white circles).

ORCID iDs

McKie, Ross, Murphy, J.A., Park, S.R., Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677 and Zhou, S.;
  • Item type:Article
    ID code:9895
    Dates:
    Date
    Event
    27 August 2007
    Published
    23 July 2007
    Published Online
    Notes:1A. J. Arduengo III, R. L. Harlow, M. Kline, J. Am. Chem. Soc. 1991, 113, 361–363.CrossRef,CAS,Web of Science® Times Cited: 1216 2W. A. Herrmann, Angew. Chem. 2002, 114, 1342–1363; Direct Link:AbstractFull Article (HTML)PDF(495K)ReferencesAngew. Chem. Int. Ed. 2002, 41, 1290–1309.Direct Link:AbstractFull Article (HTML)PDF(1434K)References 3For example: 3aA. D. Tulloch, A. A. Danopoulos, R. P. Tooze, S. M. Cafferkey, S. Kleinhenz, M. B. Hursthouse, Chem. Commun. 2000, 1247–1248; CrossRef,CAS,Web of Science® Times Cited: 112 3bV. César, S. Bellamin-Laponnaz, L. H. Gade, Organometallics 2002, 21, 5204–5208; CrossRef,CAS,Web of Science® Times Cited: 853cH. M. Lee, J. Y. Zeng, C.-H. Hu, M.-T. Lee, Inorg. Chem. 2004, 43, 6822–6829; CrossRef,PubMed,CAS,Web of Science® Times Cited: 73 3dA. A. Danopoulos, S. Winston, T. Gelbrich, M. B. Hursthouse, R. P. Tooze, Chem. Commun. 2002, 482–483.CrossRef,PubMed,CAS,Web of Science® Times Cited: 50 4P. B. Hitchcock, M. F. Lappert, P. Terreros, K. P. Wainwright, J. Chem. Soc. Chem. Commun. 1980, 1180–1181.CrossRef,CAS,Web of Science® Times Cited: 495 5aM. V. Baker, S. K. Brayshaw, B. W. Skelton, A. H. White, C. C. Williams, J. Organomet. Chem. 2005, 690, 2312–2322, and references therein; CrossRef,CAS,Web of Science® Times Cited: 20 5bA. Melaiye, Z. Sun, K. Hindi, A. Milsted, D. Ely, D. H. Reneker, C. A. Tessier, W. J. Youngs, J. Am. Chem. Soc. 2005, 127, 2285–2291, and references therein.CrossRef,PubMed,CAS,Web of Science® Times Cited: 121 6M. V. Baker, B. W. Skelton, A. H. White, C. C. Williams, Organometallics 2002, 21, 2674–2678.CrossRef,CAS,Web of Science® Times Cited: 42 7F. E. Hahn, V. Langenhahn, T. Lügger, T. Pape, D. Le Van, Angew. Chem. 2005, 117, 3825–3829; Direct Link:AbstractFull Article (HTML)PDF(336K)ReferencesAngew. Chem. Int. Ed. 2005, 44, 3759–3763.Direct Link:AbstractFull Article (HTML)PDF(337K)References 8aJ. A. Murphy, S.-z. Zhou, D. W. Thomson, F. Schoenebeck, M. Mahesh, S. R. Park, T. Tuttle, L. E. A. Berlouis, Angew. Chem. 2007, 119, 5270–5275; Direct Link:AbstractFull Article (HTML)PDF(222K)ReferencesAngew. Chem. Int. Ed. 2007, 46, 5178–5183; Direct Link:AbstractFull Article (HTML)PDF(223K)References 8bW. H. W. Wong, M. S. Vickers, A. R. Cowley, R. L. Paul, P. D. Beer, Org. Biomol. Chem. 2005, 4201–4208.CrossRef,PubMed,CAS,Web of Science® Times Cited: 23 9I. J. B. Lin, C. S. Vasam, Comments Inorg. Chem. 2004, 25, 75–129.CrossRef,CAS,Web of Science® Times Cited: 76 10D. A. Fletcher, R. F. McMeeking, D. J. Parkin, J. Chem. Inf. Comput. Sci. 1996, 36, 746–749.CAS,Web of Science® Times Cited: 891 11For example: H. M. J. Wang, I. J. B. Lin, Organometallics 1998, 17, 972–975.CrossRef,CAS,Web of Science® Times Cited: 347 12aG. Helgesson, S. Jagner, J. Chem. Soc. Dalton Trans. 1990, 2413–2420; CrossRef,CAS,Web of Science® Times Cited: 35 12bS. Olson, G. Helgesson, S. Jagner, Inorg. Chim. Acta 1994, 217, 15–20; CrossRef,CAS,Web of Science® Times Cited: 19 12cJ. Estienne, Acta Crystallogr. Sect. C 1986, 42, 1512–1516.Direct Link:AbstractFull Article (HTML)PDF(607K) 13W. P. Fehlhammer, T. Bliss, J. Fuchs, G. Holzmann, Z. Naturforsch. B 1992, 47, 79–89.CAS,Web of Science® Times Cited: 21 14Complete experimental details, a summary of the crystallographic data, and spectroscopic characterization are available in the Supporting Information. 15CCDC-644573 (Ag complex), CCDC-644574 (tetraimidazolium salt), CCDC-644575 (Cu complex) and CCDC-644576 (Pd complex) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data_request/cif.
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Strathprints Administrator
    Date deposited:26 Jan 2012 05:13
    Last modified:30 Aug 2024 01:43
    URI:https://strathprints.strath.ac.uk/id/eprint/9895
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