Highly efficient reduction of unactivated aryl and alkyl iodides by a ground-state neutral organic electron donor

Murphy, J.A. and Khan, T.A. and Zhou, S. and Mohan, M. and Thomson, D.W. (2005) Highly efficient reduction of unactivated aryl and alkyl iodides by a ground-state neutral organic electron donor. Angewandte Chemie, 44 (9). pp. 1356-1360. ISSN 1521-3773 (http://dx.doi.org/10.1002/anie.200462038)

Abstract

Electron-transfer reductions of unactivated aryl and alkyl iodides with a neutral ground-state organic molecule are reported. The reducing agent 1 is formed in two steps from N-methylbenzimidazole using very simple chemistry, and subsequent treatment of the iodoalkane or -arene with 1 affords cyclized products (see scheme).

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• Item metadata

  Item type:	Article
  ID code:	9884
  Dates:	Date Event 2005 Published
  Notes:	PV: 21365
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Unknown Department
  Depositing user:	Strathprints Administrator
  Date deposited:	14 Nov 2011 11:43
  Last modified:	03 Jan 2025 16:49
  URI:	https://strathprints.strath.ac.uk/id/eprint/9884