Enhanced tribological properties of diesel-based engine oil through synergistic MoS2-graphene nanohybrid additive

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Nagarajan, Thachnatharen and Sridewi, Nanthini and Wong, Weng Pin and Walvekar, Rashmi and Khalid, Mohammad (2023) Enhanced tribological properties of diesel-based engine oil through synergistic MoS2-graphene nanohybrid additive. Scientific Reports, 13 (1). 17424. ISSN 2045-2322 (https://doi.org/10.1038/s41598-023-43260-1)

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Abstract

This research explores the potential of microwave-synthesized MoS2-graphene nanohybrid as additives to enhance the tribological properties of diesel-based engine oil. The synthesis method offers significant advantages, reducing both synthesis time and energy consumption by 90–98% compared to conventional approaches. The synthesized nanohybrids are characterized through FESEM, EDX, XRD, and Raman spectroscopy to understand their morphology and functional group interactions. These nanohybrids are incorporated into 20W40 engine oil following synthesis, and a comprehensive assessment of their properties is conducted. This evaluation covers critical parameters like viscosity index, stability, volatility, as well as tribological properties, oxidation resistance, and thermal conductivity of the oil-nanohybrid system. Results demonstrate that adding just 0.05 wt% of MoS2-graphene nanohybrid leads to a remarkable 58.82% reduction in friction coefficient and a significant 36.26% decrease in the average wear scar diameter. Additionally, oxidation resistance improves by 19.21%, while thermal conductivity increases notably by 19.83% (at 100 °C). The study demonstrates the synergistic effects of these nanohybrids in reducing friction and wear, enhancing oxidation resistance, and improving thermal conductivity. In conclusion, this research highlights the potential of microwave-synthesized MoS2-graphene nanohybrid as promising tribological additives for diesel engine oils. Their successful integration could significantly enhance the performance and durability of critical mechanical components in diesel engines, representing a significant advancement in lubrication technology.

ORCID iDs

Nagarajan, Thachnatharen, Sridewi, Nanthini, Wong, Weng Pin, Walvekar, Rashmi ORCID logoORCID: https://orcid.org/0000-0001-8283-1278 and Khalid, Mohammad;
CORE (COnnecting REpositories)