Synthetic molecular photoelectrochemistry : new frontiers in synthetic applications, mechanistic insights and scalability

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Wu, Shangze and Kaur, Jaspreet and Karl, Tobias A. and Tian, Xianhai and Barham, Joshua P. (2022) Synthetic molecular photoelectrochemistry : new frontiers in synthetic applications, mechanistic insights and scalability. Angewandte Chemie - International Edition, 61 (12). e202107811. ISSN 1521-3773 (https://doi.org/10.1002/anie.202107811)

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Abstract

Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. Herein, the most recent contributions are reviewed, demonstrating exciting new opportunities, namely, the combination of PEC with other reactivity paradigms (hydrogen-atom transfer, radical polar crossover, energy transfer sensitization), scalability up to multigram scale, novel selectivities in SET super-oxidations/reductions and the importance of precomplexation to temporally enable excited radical ion catalysis.

ORCID iDs

Wu, Shangze, Kaur, Jaspreet, Karl, Tobias A., Tian, Xianhai and Barham, Joshua P. ORCID logoORCID: https://orcid.org/0000-0003-1675-9399;
  • Item type:Article
    ID code:92117
    Dates:
    Date
    Event
    14 March 2022
    Published
    9 February 2022
    Published Online
    3 September 2021
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:20 Feb 2025 11:53
    Last modified:20 Feb 2025 15:21
    URI:https://strathprints.strath.ac.uk/id/eprint/92117
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