An energy-efficient cyclic amine system developed for carbon capture from both flue gas and air

Lu, Guanchu and Yue, Zongyang and Deng, Yanan and Xue, Yuxiang and Huang, Yi and Zhang, Xiaolei and Chen, Xianfeng and Fan, Xianfeng (2024) An energy-efficient cyclic amine system developed for carbon capture from both flue gas and air. Chemical Engineering Journal, 496. 154085. ISSN 1385-8947 (https://doi.org/10.1016/j.cej.2024.154085)

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Abstract

High energy consumption is a major barrier to the large-scale deployment of carbon capture processes from flue gases or air (direct air capture, DAC). The non-aqueous amines reported in literature possess a high energy efficiency for CO2 capture from flue gases, they struggle with gas streams containing ultra-dilute CO2, like air, due to poor absorption kinetics. This study developed novel 2-PE (2-piperidineethanol)/APZ (Aminoethylpiperazine) based CO2 absorbents to address these problems. The experiments and MD simulation results showed that the 2-PE/APZ-based absorbents possessed a superior absorption performance both in flue gas and air. Among the developed absorbents, when 2-PE/APZ mixed with DMF (Dimethylformamide), the CO2 loading reached to 1.004 mol/mole, as the theoretical maximum. In DAC tests, 87.31 % CO2 from the air was captured in 24 h experiments. The regeneration heat duty of 2-PE/APZ/DMF decreased to 1.694 KJ/g CO2, a 55.89 % reduction compared to the benchmark 30 wt% MEA. The CO2 absorption/desorption mechanism was analysed by NMR, In-situ FT-IR, and DFT calculation. It indicated that this significant improvement in CO2 absorption performance and the reduction in energy consumption are due to the synergistic effect of 2-PE and APZ. During CO2 absorption, CO2 reacts with APZ forming APZ zwitterion rapidly, then deprotonation to the 2-PE. The formation of protonated 2-PEH+ ion pairs with APZCOO- reduces hydrogen bonds and van der Waals forces among the amine-CO2 complex, facilitating easy regeneration at mild conditions while maintaining high reactivity. The combination of theoretical and experimental results indicates that 2-PE/APZ-based absorbents can serve as a promising alternative for carbon capture from flue gas to air with low energy usage.

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