Size-dependent stability of ultra-small α-/β-phase tin nanocrystals synthesized by microplasma

Haq, Atta Ul and Askari, Sadegh and McLister, Anna and Rawlinson, Sean and Davis, James and Chakrabarti, Supriya and Svrcek, Vladimir and Maguire, Paul and Papakonstantinou, Pagona and Mariotti, Davide (2019) Size-dependent stability of ultra-small α-/β-phase tin nanocrystals synthesized by microplasma. Nature Communications, 10. 817. ISSN 2041-1723 (https://doi.org/10.1038/s41467-019-08661-9)

[thumbnail of ul-Haq-et-al-Size-dependent-stability-of-ultra-small]
Preview
 Text. Filename: ul-Haq-et-al-Size-dependent-stability-of-ultra-small.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo
Download (1MB)| Preview

Abstract

Nanocrystals sometimes adopt unusual crystal structure configurations in order to maintain structural stability with increasingly large surface-to-volume ratios. The understanding of these transformations is of great scientific interest and represents an opportunity to achieve beneficial materials properties resulting from different crystal arrangements. Here, the phase transformation from α to β phases of tin (Sn) nanocrystals is investigated in nanocrystals with diameters ranging from 6.1 to 1.6 nm. Ultra-small Sn nanocrystals are achieved through our highly non-equilibrium plasma process operated at atmospheric pressures. Larger nanocrystals adopt the β-Sn tetragonal structure, while smaller nanocrystals show stability with the α-Sn diamond cubic structure. Synthesis at other conditions produce nanocrystals with mean diameters within the range 2–3 nm, which exhibit mixed phases. This work represents an important contribution to understand structural stability at the nanoscale and the possibility of achieving phases of relevance for many applications.

ORCID iDs

Haq, Atta Ul, Askari, Sadegh, McLister, Anna, Rawlinson, Sean, Davis, James, Chakrabarti, Supriya, Svrcek, Vladimir, Maguire, Paul, Papakonstantinou, Pagona and Mariotti, Davide ORCID logoORCID: https://orcid.org/0000-0003-1504-4383;
CORE (COnnecting REpositories)