Theory of Rayleigh–Brillouin optical activity light scattering applicable to chiral liquids

Cameron, Robert P. and Alexakis, Emmanouil I. and Arnold, Aidan S. and McArthur, Duncan (2024) Theory of Rayleigh–Brillouin optical activity light scattering applicable to chiral liquids. Physical Chemistry Chemical Physics, 26 (15). pp. 11641-11648. ISSN 1463-9084 (https://doi.org/10.1039/D3CP05109A)

[thumbnail of Cameron-etal-PCCP-2024-Theory-of-Rayleigh-Brillouin-optical-activity-light-scattering-applicable-to-chiral-liquids]
Preview
Text. Filename: Cameron-etal-PCCP-2024-Theory-of-Rayleigh-Brillouin-optical-activity-light-scattering-applicable-to-chiral-liquids.pdf
Final Published Version
License: Creative Commons Attribution 3.0 logo

Download (2MB)| Preview

Abstract

It has long been understood that dilute samples of chiral molecules such as rarefied gases should exhibit Rayleigh optical activity. We extend the existing theory by accounting for molecular dynamics and correlations, thus obtaining a more general theory of Rayleigh–Brillouin optical activity applicable to dense samples such as neat liquids.

ORCID iDs

Cameron, Robert P. ORCID logoORCID: https://orcid.org/0000-0002-8809-5459, Alexakis, Emmanouil I., Arnold, Aidan S. ORCID logoORCID: https://orcid.org/0000-0001-7084-6958 and McArthur, Duncan ORCID logoORCID: https://orcid.org/0000-0001-8603-8349;