Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes

Ojea, María José Heras and Wilson, Claire and Coles, Simon J. and Tuna, Floriana and Murrie, Mark (2015) Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes. Dalton Transactions. pp. 19275-19281. ISSN 1477-9226 (https://doi.org/10.1039/c5dt03344f)

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Abstract

The polydentate ligand Bis–tris propane is used to assemble two Cu/Zn heterometallic complexes: a tetramer which displays an unusually strong Cu(ii)⋯Cu(ii) exchange given the Cu⋯Cu separation or, in the presence of base, a hexadecanuclear complex with a remarkable double-concentric ring structure.

ORCID iDs

Ojea, María José Heras ORCID logoORCID: https://orcid.org/0000-0002-9290-5178, Wilson, Claire, Coles, Simon J., Tuna, Floriana and Murrie, Mark;
CORE (COnnecting REpositories)