Rendering polyurethane hydrophilic for efficient cellulose reinforcement in melt-spun nanocomposite fibers
Redondo, Alexandre and Bast, Livia K. and Djeghdi, Kenza and Airoldi, Martino and Jang, Daseul and Korley, LaShanda T. J. and Steiner, Ullrich and Bruns, Nico and Gunkel, Ilja (2023) Rendering polyurethane hydrophilic for efficient cellulose reinforcement in melt-spun nanocomposite fibers. Advanced Materials Interfaces, 10 (9). 2201979. ISSN 2196-7350 (https://doi.org/10.1002/admi.202201979)
Preview |
Text.
Filename: Redondo_etal_AMI_2023_Rendering_polyurethane_hydrophilic_for_efficient_cellulose_reinforcement.pdf
Final Published Version License: Download (3MB)| Preview |
Abstract
Many commodity plastics, such as thermoplastic polyurethanes (PUs), require reinforcement for use as commercial products. Cellulose nanocrystals (CNCs) offer a “green” and scalable approach to polymer reinforcement as they are exceptionally stiff, recyclable, and abundant. Unfortunately, achieving efficient CNC reinforcement of PUs with industrial melt processing techniques is difficult, mostly due to the incompatibility of the hydrophobic PU with hydrophilic CNCs, limiting their dispersion. Here, a hydrophilic PU is synthesized to achieve strong reinforcement in melt‐processed nanocomposite fibers using filter paper‐sourced CNCs. The melt‐spun fibers, exhibiting smooth surfaces even at high CNC loading (up to 25 wt%) indicating good CNC dispersion, are bench‐marked against solvent‐cast films—solvent processing is not scalable but disperses CNCs well and produces strong CNC reinforcement. Mechanical analysis shows the CNC addition stiffens both nanocomposite films and fibers. The stress and strain at break, however, are not significantly affected in films, whereas adding CNCs to fibers increases the stress‐at‐break while reducing the strain‐at‐break. Compared to earlier studies employing a hydrophobic (and stiffer) PU, CNC addition to a hydrophilic PU substantially increases the fiber stiffness and strength. This work therefore suggests that rendering thermoplastics more hydrophilic might pave the way for “greener” polymer composite products using CNCs.
ORCID iDs
Redondo, Alexandre, Bast, Livia K., Djeghdi, Kenza, Airoldi, Martino, Jang, Daseul, Korley, LaShanda T. J., Steiner, Ullrich, Bruns, Nico ORCID: https://orcid.org/0000-0001-6199-9995 and Gunkel, Ilja;-
-
Item type: Article ID code: 84312 Dates: DateEvent24 March 2023Published19 February 2023Published Online29 December 2022Accepted6 September 2022SubmittedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 21 Feb 2023 12:11 Last modified: 24 Oct 2024 00:42 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/84312