Exceptional electron donating ability of an extended tetrathiafulvalene derivative

Khan, T. and Skabara, P.J. and Frere, P. and Allain, M. and Coles, S.J. and Hursthouse, M.B. (2004) Exceptional electron donating ability of an extended tetrathiafulvalene derivative. Tetrahedron Letters, 45 (12). pp. 2535-2539. ISSN 0040-4039 (http://dx.doi.org/10.1016/j.tetlet.2004.02.003)

Abstract

We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.

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• Item metadata

  Item type:	Article
  ID code:	843
  Dates:	Date Event 15 March 2004 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	21 Apr 2006
  Last modified:	11 Nov 2024 08:27
  Related URLs:	http://www.sciencedirect.com/science?_ob...
  URI:	https://strathprints.strath.ac.uk/id/eprint/843