Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

Donnelly, Liam J. and Parsons, Simon and Morrison, Carole A. and Thomas, Stephen P. and Love, Jason B. (2020) Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis. Chemical Science, 11 (36). pp. 9994-9999. ISSN 2041-6520 (https://doi.org/10.1039/d0sc03458d)

[thumbnail of Donnelly-etal-CS-2020-Synthesis-and-structures-of-anionic-rhenium-polyhydride-complexes-of-boron–hydride-ligands]
Preview
Text. Filename: Donnelly_etal_CS_2020_Synthesis_and_structures_of_anionic_rhenium_polyhydride_complexes_of_boron_hydride_ligands.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo

Download (952kB)| Preview

Abstract

Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.