Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

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Donnelly, Liam J. and Parsons, Simon and Morrison, Carole A. and Thomas, Stephen P. and Love, Jason B. (2020) Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis. Chemical Science, 11 (36). pp. 9994-9999. ISSN 2041-6539 (https://doi.org/10.1039/d0sc03458d)

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Abstract

Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.

ORCID iDs

Donnelly, Liam J. ORCID logoORCID: https://orcid.org/0000-0003-3342-4902, Parsons, Simon, Morrison, Carole A., Thomas, Stephen P. and Love, Jason B.;
CORE (COnnecting REpositories)