Photoactive carbon monoxide-releasing coordination polymer particles

Carné-Sánchez, Arnau and Ikemura, Shuya and Sakaguchi, Reiko and Craig, Gavin A. and Furukawa, Shuhei (2022) Photoactive carbon monoxide-releasing coordination polymer particles. Chemical Communications, 58 (71). pp. 9894-9897. ISSN 1359-7345 (https://doi.org/10.1039/D2CC03907A)

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Abstract

We report the synthesis of photoactive carbon monoxide-releasing coordination polymer particles through the assembly of Mn(i) carbonyl complexes with bis(imidazole) ligands. The use of Mn(i) carbonyl complexes as metallic nodes in the coordination network avoids the potential for aggregation-induced self-quenching, favouring their use in the solid state.