A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

Khan, T. and Skabara, P.J. and Coles, S.J. and Hursthouse, M.B. (2001) A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. Chemical Communications (London), 2001 (4). pp. 369-370. ISSN 0009-241X

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Abstract

In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

Author(s):Khan, T., Skabara, P.J., Coles, S.J. and Hursthouse, M.B.
Item type:Article
ID code:805
Keywords:chemistry, perchloric acid, thiones, Chemistry, Chemistry(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Mr Derek Boyle
Date deposited:19 Apr 2006
Last modified:03 Jan 2019 11:14
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URI:https://strathprints.strath.ac.uk/id/eprint/805
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