A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement
Khan, T. and Skabara, P.J. and Coles, S.J. and Hursthouse, M.B. (2001) A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. Chemical Communications (London), 2001 (4). pp. 369-370. ISSN 0009-241X
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Abstract
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
Author(s): | Khan, T., Skabara, P.J., Coles, S.J. and Hursthouse, M.B. | Item type: | Article |
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ID code: | 805 |
Keywords: | chemistry, perchloric acid, thiones, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 19 Apr 2006 |
Last modified: | 03 Jan 2019 11:14 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/805 |
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