Polymerizable UV absorbers for the UV stabilization of polyesters. I. Design, synthesis and polymerization of a library of UV absorbing monomers

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Cormack, Peter A. G. and Erdemli, Omer Can and Sankey, Stephen W. (2021) Polymerizable UV absorbers for the UV stabilization of polyesters. I. Design, synthesis and polymerization of a library of UV absorbing monomers. Arkivoc (6). pp. 148-173. ISSN 1551-7004 (https://doi.org/10.24820/ark.5550190.p011.575)

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Abstract

Poly(ethylene terephthalate) (PET) absorbs strongly in the ultraviolet (UV) region of the EM spectrum (Figure 1), and this can lead to photodegradation of the polymer chains and loss of polymer properties. UV stabilizer additives are normally employed to suppress the UV-induced photodegradation of polyester films, especially for those applications where the levels of UV exposure to the polymer film are high, e.g., photovoltaic cells. One limitation concerning the use of UV stabilizers is the loss of additive from the polymers over time by leaching, since UV stabilizers are normally low molar mass organic compounds that can be washed out through weathering actions, and this reduces their effectiveness. One way in which this leaching problem can potentially be circumvented is to lock the UV stabilizers into the polymer chains through covalent bonds

ORCID iDs

Cormack, Peter A. G. ORCID logoORCID: https://orcid.org/0000-0002-3390-8176, Erdemli, Omer Can ORCID logoORCID: https://orcid.org/0000-0002-4179-0112 and Sankey, Stephen W.;
  • Item type:Article
    ID code:77885
    Dates:
    Date
    Event
    16 September 2021
    Published
    8 August 2021
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:23 Sep 2021 13:01
    Last modified:17 Dec 2024 01:23
    URI:https://strathprints.strath.ac.uk/id/eprint/77885
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